Product ID:4500 SERIES-EXTREME HIGH GLOSS URETHANE (SUPDAT)
MSDS Date:06/09/1993
FSC:8010
NIIN:00N055028
MSDS Number: BVYZV

PRO-LINE PAINT CO

2646 MAIN ST
SAN DIEGO, CA 92113-3697
US

Emergency Phone: 619-728-3192

Info Phone: 619-231-2313

Preparer: E. SOETERIK

Cage: 9D157

PRO-LINE PAINT CO

SAN DIEGO, CA 92113-3697 US

Telephone: 619-231-2313; 619-232-8968

Cage: 9D157

COMPONENT B CONTAINING INGS 2-11

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

ETHANE, 1,1,1-TRICHLORO-; (1,1,1, TRICHLOROETHANE) (SARA

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 19.6%

OSHA PEL 350 PPM; 450 STEL

ACGIH TLV: 350 PPM; 450 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHANOL, 2-(2-METHOXYETHOXY)-; (METHYL CARBITOL SOLVENT)

CAS: 111-77-3

RTECS: KL6125000

Fraction By Weight: 4.6%

OSHA PEL N/K

ACGIH TLV: N/K

2-HEPTANONE; (METHYL AMYL KETONE)

CAS: 110-43-0

RTECS: MJ5075000

Fraction By Weight: 4.6%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM

ETHANOL, 2-BUTOXY-; (BUTYL CELLOSOLVE)

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: 2.3%

OSHA PEL 50 PPM, S

ACGIH TLV: 25 PPM, S

RESIN CONTAINING INGS 7 & 8

Fraction By Weight: 20%

OSHA PEL N/K

ACGIH TLV: N/K

ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER;

CAS: 108-65-6

RTECS: AI8295000

Fraction By Weight: 30%

OSHA PEL N/K

ACGIH TLV: N/K

XYLENE (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 5-15%

OSHA PEL 100 PPM; 150 STEL

ACGIH TLV: 100 PPM; 150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

POLYESTER POLYOL CONTAINING ING 10

Fraction By Weight: 2%

OSHA PEL N/K

ACGIH TLV: N/K

ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER;

CAS: 108-65-6

RTECS: AI8295000

Fraction By Weight: 25%

OSHA PEL 100 PPM (MFR)

ACGIH TLV: 100PPM; 150STEL(MFR)

RUTILE; (RUTILE TITANIUM DIOXIDE)

CAS: 1317-80-2

RTECS: VM2940000

Fraction By Weight: 25.5%

OSHA PEL N/K

ACGIH TLV: 10 MG/M3 DUST (MFR)

COMPONENT A CONSISTING OF INGS 13-17

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

ALIPHATIC POLYISOCYANATE CONTAINING INGS 14-17

Fraction By Weight: 20%

OSHA PEL N/K

ACGIH TLV: N/K

ISOCYANIC ACID, HEXAMETHYLENE ESTER, POLYMERS; (HOMOPOLYMER

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 75%

OSHA PEL N/K

ACGIH TLV: N/K

HEXANE, 1,6-DIISOCYANATO-; (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

Fraction By Weight: SEE ING

OSHA PEL N/K

ACGIH TLV: 0.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

XYLENE (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 12.5%

OSHA PEL 100 PPM; 150 STEL

ACGIH TLV: 100 PPM; 150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ACETIC ACID, BUTYL ESTER; (N BUTYL ACETATE) (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 12.5%

OSHA PEL 150 PPM; 200 STEL

ACGIH TLV: 150 PPM; 200 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

420 G/L

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

2-BUTOXYETHANOL . PERS W/ASTHMATIC-TYPE CNDTNS,

RTECS: 9999999ZZ

SKIN DISEASE SHOULD BE EXCLUDED FROM WORKING

RTECS: 9999999ZZ

OVEREXP TO SOLVENTS CAN CAUSE PERM BRAIN & NERVOUS

RTECS: 9999999ZZ

THE CONTENTS MAY BE HARMFUL OR FATAL.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE LISTED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:CHLOROCARBON MATLS HAVE PRDCED
SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE
SIMILAR EFT IN HUMANS. ADRENOMIMETICS (EG, EPINEPHRINE) MAY BE
CONTRA-INDICATED EXCEPT FOR LIFE-SUS TAINING USES IN HUMANS
ACUTELY/CHRONICALLY EXPOS TO CHLOROCARBONS . INHAL: INHAL OF HIGHER
CONCS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:MAY CAUSE HDCH, NAUS, VOMIT & COMA.
VERY HIGH CONC MAY CAUSE UNCON/DEATH. SKIN/EYE CNTCT: BURNING
SENSATION FROM VAP/LIQ. DERM, SENSIT. ABSORPTION: DEFAT OF SKIN CAN
LEAD TO MORE SERIOUS SKIN INFECTIONS. INGEST: TOX IF SWALLOWED.
CAN CAUSE BURNING SENSATION, VOMIT, DIARR, DROW. CHRONIC: ANIMAL
STUDIES (SUPDAT)
Medical Cond Aggravated by Exposure:ASTHMA AND SKIN ALLERGIES.

First Aid:EYES: FLUSH IMMED W/FRESH WATER BY EYE WASH APPARATUS OR BY
HAND FOR AT LEAST 15 MIN. SEEK MED ATTN. SKIN: WASH IMMED W/WATER.
THEN WASH W/SOAP & WATER. RINSE IMMED. SEEK MED ATTN. INHAL: MOVE
PERSON TO FRESH AIR; ARTF RESP IF NECESSARY. SEEK MED ATTN.
INGEST: SEEK MED ATTN. RECOM TO MD: IN ACUTE CASES SEEK MED ATTN
IMMED. FOR WORKERS WHO MAY BE EXPOS REGULARLY; PROVIDE DETAILED
PERIODIC EXAMS.

Flash Point Method:TCC
Flash Point:26.0F,-3.3C
Lower Limits:1.1%
Upper Limits:22%
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD PRESS DEMAND SCBA &
FULL PROT EQUIP. BLANKET FLAME W/ONE OF EXTING. VAPS OF COMBUST MAY
BE IRRIT TO RESP TRACT. MAY CAUSE (SUPDAT)
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL AND PHOSGENE . KEEP MATERIAL AWAY FROM HEAT, SPARKS AND
OPEN FLAMES.

Spill Release Procedures:REMOVE ALL TYPES OF IGNITION SOURCES. PROVIDE
SUFFICIENT VENTILATION. PROTECT CLEAN-UP PERSON WITH 8540 3M CORP
RESPIRATOR (NIOSH/MSHA APPROVED) AND GOGGLES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DAMAGE TO
CONTAINERS & SPILLAGE. STORE IN COOL, WELL VENT AREA W/SPRINKLER
SYS. KEEP AWAY FROM HEAT. POST NO SMKNG SIGNS.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE . USE
ONLY WITH ADEQUATE VENTILATION.

Respiratory Protection:USE NIOSH/MSHA APPRVD DUST/MIST RESP (HIGH
EFFICIENCY CARTRIDGES ADVISED) IF SPRAYING/SANDING. USE NIOSH/MSHA
APPRVD ORG VAP CARTRIDGE RESP IF TLV MAY BE EXCEEDED E.G. 8540 3M
CORP RESP. USE AIR-FED H OOD WHEN SPRAYING IN CONFINED AREAS.
Ventilation:USE LOCAL EXHAUST WHEN APPLYING THIS PAINT IN CONFINED
AREAS. KEEP VAPORS BELOW TLV.
Protective Gloves:SOLVENT RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:PROT CLTHG & CHANGE CONTAMD CLTHG IMMED.
PROVIDE EMER SHOWERS & EYEWASH AT STATIONARY PAINT APPLICATION
FACILITIES.
Work Hygienic Practices:TRAIN EMPLOYEES ON ALL SPECIAL HANDLING
PROCEDURES BEFORE THEY WORK WITH THIS PRODUCT.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO: VARNISH LINEAR POLYURETHANE PAINT-WHITE &
COLORS - LEAD & CHROME FREE. FIRE FIGHT PROC: BRTHG DFCLTIES. PVNT
HUMAN EXPOS TO FIRE, SMOKE, FUMES, ETC. EFTS OF OVEREXP: HAVE CLE
ARLY SHOWN DOSE-RELATED ADVERSE EFTS TOCNS, HEMATOPOIETIC TISS,
BLOOD, KIDNEYS & LIVER ASSOC W/ADMIN OF (ING 19)

HCC:F3
Boiling Pt:B.P. Text:126F,52C
Vapor Pres:59.16 @20C
Vapor Density:3.89
Spec Gravity:1.38
Evaporation Rate & Reference:1.03 (BUTYL ACETATE=1)
Solubility in Water:PARTIAL
Appearance and Odor:VISCOUS LIQUID WITH AROMATIC HYDROCARBON ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, SPARKS & OPEN FLAMES. DO NOT ALLOW
VAPORS TO ACCUMULATE.
Hazardous Decomposition Products:HCL,PHOSGENE FLAM FUMES MAY ACCUM IN
CONFINED AREA & SPK/OPEN FLAMES MAY IGNITE IT. CO2, CO, OXIDES OF
NITROGEN.

Waste Disposal Methods:USE METAL CONTAINER MARKED "DO NOT REUSE." PUT
THE MATERIAL IN THIS CONTAINER. USE VERMICULITE OR OTHER INERT
ABSORBENT. KEEP AWAY FROM SEWER. DISPOSE OF ALL WASTES IN
ACCORDANCE WITH FEDERAL, STATE A ND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.